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Haugaard SB, Andersen O, Hansen BR, Orskov H, Andersen UB, Madsbad S, Iversen J, Flyvbjerg A: Insulin-like growth factors, insulin-like growth factor-binding proteins, insulin-like growth factor-binding protein-3 protease, and growth hormone-binding protein in lipodystrophic human immunodeficiency virus-infected patients

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At physiological pH, the cysteine thiol (pKa ~8) is substantially more nucleophilic than the lysine amine (pKa ~10.5), making non-enzymatic acetylation of cysteine thermodynamically and kinetically favored 31